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A facile one-pot solvothermal route to tubular forms of luminescent polymeric networks [(C3N3)2(NH)3]n by Qixun Guo; Qing Yang; Lei Zhu; Chengqi Yi; Shuyuan Zhang; Yi Xie is a Physics and Astronomy article available to read on EtoBox.

What is A facile one-pot solvothermal route to tubular forms of luminescent polymeric networks [(C3N3)2(NH)3]n about?

A facile one-pot solvothermal route has been developed for the synthesis of tubular luminescent polymeric networks [(C 3 N 3 ) 2 (NH) 3 ] n , structurally related to the proposed g-C 3 N 4 . XRD patterns showed a characteristic 002 basal plane diffractions, indicating an interlayer d spacing of 3.23 A ̊. XPS spectra show that the C1s and N1s have a symmetric peak and an asymmetric peak at 288.10 and 399.00 eV, respectively. The bulk composition C 6 N 8.9 H 4.5 determined by elemental analysis is comparable to the calculated value C 6 N 9 H 3 for this proposed polymer. FTIR spectra indicated the presence of s-triazine ring, which was further supported by the luminescent and UV-vis absorption characteristics probably depending on p/p \* electronic transition. The tubular structure has been studied by TEM, SAED, and HREM.

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Author

Qixun Guo; Qing Yang; Lei Zhu; Chengqi Yi; Shuyuan Zhang; Yi Xie

Publisher

Elsevier Science; Elsevier ; Elsevier BV (ISSN 0038-1098)

Published

2004

Language

EN

Field

Physics and Astronomy (Physical Sciences)