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Can I read Formal total synthesis of histrionicotoxin alkaloids via Hg(OTf)~2~-catalyzed cycloisomerization and SmI~2~-induced ring expansion† on EtoBox?
Formal total synthesis of histrionicotoxin alkaloids via Hg(OTf)~2~-catalyzed cycloisomerization and SmI~2~-induced ring expansion† by Kunihiro Matsumura; Keisuke Nishikawa; Hiroaki Yoshida; Matsumi Doe; Yoshiki Morimoto is a Materials Science article available to read on EtoBox.
What is Formal total synthesis of histrionicotoxin alkaloids via Hg(OTf)~2~-catalyzed cycloisomerization and SmI~2~-induced ring expansion† about?
The efficient formal total synthesis of histrionicotoxin alkaloids was achieved. In this process, two key reactions were used to construct a core 1-azaspiro[5.5]undecane framework common to histrionicotoxins: a mercuric triflate (Hg(OTf)~2~)-catalyzed cycloisomerization of a linear substrate, which was developed in our laboratory, and a samarium iodide (SmI~2~)-mediated ring expansion.
Who reads Formal total synthesis of histrionicotoxin alkaloids via Hg(OTf)~2~-catalyzed cycloisomerization and SmI~2~-induced ring expansion†?
It is typically read by researchers, students, and practitioners in Materials Science.
- Author
- Kunihiro Matsumura; Keisuke Nishikawa; Hiroaki Yoshida; Matsumi Doe; Yoshiki Morimoto
- Publisher
- The Royal Society of Chemistry
- Published
- 2018
- Language
- EN
- Field
- Materials Science (Physical Sciences)