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What is Enantioselective Azamerone Synthesis about?
This document describes a concise and enantioselective synthesis of the meroterpenoid natural product azamerone. Key challenges included developing strategies to access chiral organochloride motifs. The synthesis features a novel enantioselective chloroetherification reaction, a Pd-catalyzed cross-coupling of a quinone diazide and boronic hemiester, and a late-stage tetrazine [4+2]-cycloaddition/oxidation cascade. This route addresses a need for syntheses of highly oxidized and densely functionalized haloge
- Author
- Etherion Eruto Phoenhaimu
- Language
- EN