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Can I read Cr(VI) quantification using an amperometric enzyme-based sensor: Interference and physical and chemical factors controlling the biosensor response in ground waters on EtoBox?
Cr(VI) quantification using an amperometric enzyme-based sensor: Interference and physical and chemical factors controlling the biosensor response in ground waters by Caroline Michel; Aziz Ouerd; Fabienne Battaglia-Brunet; Nathalie Guigues; Jean-Pierre Grasa; Mireille Bruschi; Ioannis Ignatiadis is a Engineering article available to read on EtoBox.
What is Cr(VI) quantification using an amperometric enzyme-based sensor: Interference and physical and chemical factors controlling the biosensor response in ground waters about?
The development of an amperometric enzyme-based sensor for chromate (CrO 4 2-) quantification in ground waters was investigated. Crucial physical and chemical factors characterising ground waters were tested for their influence or interference on chromate quantification: pH (7.6-8.5), temperature (9-25 • C), ionic strength (0-0.2 M), oxygen, metals, bicarbonate and sulphate. The biosensor's response was dependent on temperature and pH as sensitivity increased with temperature and was higher at pH 7.6 than at pH 8.5. Sensitivity decreased with ionic strength until 0.1 M, and was stable for higher values. Dissolved oxygen did not allow chromate quantification when it was present, but O 2 could be eliminated by adding Na 2 SO 3 or bubbling nitrogen gas into the solution. Bicarbonate did not interfere with chromate quantification by the biosensor. Sulphate was detected with a detection threshold 80 times higher than that of chromate and a lower sensitivity. Several metals (V(V), W(VI), Mn(VII), Mo(VI)) similar to chromate due to their oxidative properties and structure (oxyanions) were tested as possible interfering compounds. The sensitivity of the biosensor for these metals was low a
Who reads Cr(VI) quantification using an amperometric enzyme-based sensor: Interference and physical and chemical factors controlling the biosensor response in ground waters?
It is typically read by researchers, students, and practitioners in Engineering.
- Author
- Caroline Michel; Aziz Ouerd; Fabienne Battaglia-Brunet; Nathalie Guigues; Jean-Pierre Grasa; Mireille Bruschi; Ioannis Ignatiadis
- Publisher
- Elsevier Science; Elsevier ; Elsevier Ltd.; Elsevier BV (ISSN 0956-5663)
- Published
- 2006
- Language
- EN
- Field
- Engineering (Physical Sciences)