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General Method to Transform Chiral 2,3-Epoxyalcohols Into Erythro or Threo 1,2-Epoxyalcohols with Total Stereochemical Control by J.M Palazón; B Añorbe; V.S Martin is a Chemistry article available to read on EtoBox.

What is General Method to Transform Chiral 2,3-Epoxyalcohols Into Erythro or Threo 1,2-Epoxyalcohols with Total Stereochemical Control about?

The isomerization of chiral 2,3-epoxyalcohols from E-allylic alcohols to chiral erythro or threo 1,2-epoxyalcohols has been accomplished with good yields, perfect stereochemical control and a very high grade of generality. Epoxides are very well known intermediates in organic synthesis mainly because of their special reactivity under a wide range of reaction conditions. Special attention has been focussed, in the last few years, on this functional group due to the possibility of building chiral 2,3-epoxyalcohols from suitable allylic alcohols, in most cases with a very high grade of enantioselectivityl).

Who reads General Method to Transform Chiral 2,3-Epoxyalcohols Into Erythro or Threo 1,2-Epoxyalcohols with Total Stereochemical Control?

Author

J.M Palazón; B Añorbe; V.S Martin

Publisher

Elsevier Science; Elsevier ; Elsevier Ltd.; Elsevier BV (ISSN 0040-4039)

Published

1986

Language

EN

Field

Chemistry (Physical Sciences)