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Identification of a four-center intermediate in a Grignard addition reaction to a P–S bond by Graziano Baccolini; Carla Boga; Marzia Mazzacurati is a Chemistry article available to read on EtoBox.

What is Identification of a four-center intermediate in a Grignard addition reaction to a P–S bond about?

The reaction between tert-butylmagnesium chloride (or tert-pentylmagnesium chloride) and the particular phosphorus-sulfur bond of a benzothiadiphospholic system showed, for the first time, evidence of formation of intermediates with a four-center structure. The possibility, for the phosphorus atom, to have very stable hypervalent coordinations makes it possible to observe its hypervalent states during the course of a reaction. The benzothiadiphosphole, with its bicyclic folded structure, further stabilizes the hypervalent coordinations thus making the intermediates sufficiently stable to be detected during the course of the reaction by 31 P NMR spectroscopy, which revealed the nature and the stability of the species involved in this reaction, carried out also using other Grignard reagents.

Who reads Identification of a four-center intermediate in a Grignard addition reaction to a P–S bond?

Author

Graziano Baccolini; Carla Boga; Marzia Mazzacurati

Publisher

Elsevier Science; Elsevier ; Elsevier Ltd.; Elsevier BV (ISSN 0040-4020)

Published

2007

Language

EN

Field

Chemistry (Physical Sciences)