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06 Electrical power generation and utilization (economics, policy, supply, forecasts) Natural gas and methanol are the most economical fuels for residential fuel cell power generators as well as for mobile PEM-fuel cells. However, they have to be reformed with steam into hydrogen, which is to be cleaned from CO by shift-reaction and by partial oxidation to a level of no more than 30 ppm CO. This level is set by the Pt/Ru-C-anode of the PEMFC. A higher partial oxidation reaction rate for CO than those of Pt/Ru-C can be achieved in an oxidic Au-catalyst system. In the FeaOa-Au system, a reaction rate of 2 x lo-" mol CO/s g Au at 1000 ppm CO and 5% 'air bleed' at 80°C is achieved. This high rate allows to construct a cataylst-sheet for each cell within a PEMFC-stack. Practical and theoretical current/voltage characteristics of PEMFCs with catalyst-sheet are presented at 1000 ppm CO in Hydrogen with 5% 'air bleed'. This gives the possibility of simplifying the gas processor of the plant.

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Publisher

Elsevier Science; Elsevier ; Elsevier BV (ISSN 0140-6701)

Published

2000

Language

EN

Field

Engineering (Physical Sciences)