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Solvolyseversuche bei Verbindungen vom Typus des Δ^1,9^‐10‐Hydroxymethyl‐octalins by J. W. Rowe; A. Melera; D. Arigoni; O. Jeger; L. Ruzicka is a Chemistry article available to read on EtoBox.

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## Abstract Solvolysis of Δ^1,9^‐10‐hydroxymethyl‐octaline benzenesulfonate (XIII) yields as the chief product [0,1,4,4]‐Δ^1^‐tricyclo‐undecene (XV), the structure of which was subsequently proven by chemical means. In a competing reaction involving molecular rearrangement some bicyclic compound XVI is also found. Similarly Δ^12^‐18, 28‐cyclo compounds have been isolated in the solvolysis of Δ^13,18^‐28‐mesylates or benzenesulfonates of the oleanane series, thus supporting the view that homoallylic ring closure is the major reaction occurring in the solvolysis of compounds which contain the Δ^1,9^‐10‐hydroxymethyl‐octaline system.

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Author

J. W. Rowe; A. Melera; D. Arigoni; O. Jeger; L. Ruzicka

Publisher

John Wiley and Sons; Wiley (John Wiley & Sons); Wiley-Blackwell; Wiley (ISSN 0018-019X)

Published

1957

Language

DE

Field

Chemistry (Physical Sciences)