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This study investigates the spin delocalization and potential ferrimagnetism in atomically precise Au25(SR)018 clusters using solution 13C NMR spectroscopy. The findings reveal that electron spin density decays exponentially along alkyl chains, with position-dependent decay constants indicating significant implications for molecular spintronics. Additionally, the negative intercept temperatures in Knight shift measurements suggest localized ferrimagnetism within individual clusters.

Author
Moises Vazquez Samchez
Language
EN

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