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Synthesis and Hplc Chiral Recognition of Regioselectively Carbamoylated Cellulose Derivatives by Shouwan Tang; Xiaofang Li; Fang Wang; Guihua Liu; Yonglong Li; Fuyou Pan is a Chemistry article available to read on EtoBox.
What is Synthesis and Hplc Chiral Recognition of Regioselectively Carbamoylated Cellulose Derivatives about?
## Abstract Four regioselective‐carbamoylated cellulose derivatives having two different substituents at 2‐, 3‐, and 6‐position were prepared and evaluated as chiral stationary phases (CSPs) for high‐performance liquid chromatography. Investigations showed that the nature andarrangement of the substituents significantly influenced the chiral recognition abilities of the heterosubstituted cellulose derivatives and each derivative exhibited characteristic enantioseparation. Some racemates were better resolved on these derivatives than the corresponding homogeneously substituted cellulose derivatives including a commercial CSP, Chiralcel OD. Racemic compounds shown in this study were most effectively discriminated on cellulose2,3‐(3‐chloro‐4‐methylphenylcarbamate)‐6‐(3,5‐dimethylphenylcarbamate) and 2,3‐(3,5‐dimethylphenylcarbamate)‐6‐(3‐chloro‐4‐methylphenylcarbamate). Chirality, 2012. © 2011 Wiley Periodicals, Inc.
Who reads Synthesis and Hplc Chiral Recognition of Regioselectively Carbamoylated Cellulose Derivatives?
It is typically read by researchers, students, and practitioners in Chemistry.
- Author
- Shouwan Tang; Xiaofang Li; Fang Wang; Guihua Liu; Yonglong Li; Fuyou Pan
- Publisher
- John Wiley and Sons; Wiley (John Wiley & Sons); John Wiley & Sons Inc.; Wiley (ISSN 0899-0042)
- Published
- 2011
- Language
- EN
- Field
- Chemistry (Physical Sciences)
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