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Crystallizing Sub 10 nm Covalent Organic Framework Thin Films via Interfacial–Residual Concomitance by Ashok Kumar Mahato; Saikat Bag; Himadri Sekhar Sasmal; Kaushik Dey; Indrajit Giri; Mercedes Linares-Moreau; Carlos Carbonell; Paolo Falcaro; E. Bhoje Gowd; Ratheesh K Vijayaraghavan; Rahul Banerjee is a Chemistry article available to read on EtoBox.
What is Crystallizing Sub 10 nm Covalent Organic Framework Thin Films via Interfacial–Residual Concomitance about?
Synthesis of covalent organic framework (COF) thin films on different supports with high crystallinity and porosity is crucial for their potential applications. We have designed a new synchronized methodology, residual crystallization (RC), to synthesize sub 10 nm COF thin films. These residual crystallized COF thin films showcase high surface area, crystallinity, and conductivity at room temperature. We have used interfacial crystallization (IC) as a rate-controlling tool for simultaneous residual crystallization. We have also diversified the methodology of residual crystallization by utilizing two different crystallization pathways: fiber-to-film (F-F) and sphere-to-film (S-F). In both cases, we could obtain continuous COF thin films with high crystallinity and porosity grown on various substrates (the highest surface area of a TpAzo COF thin film being 2093 m g). Precise control over the crystallization allows the synthesis of macroscopic defect-free sub 10 nm COF thin films with a minimum thickness of ∼1.8 nm. We have synthesized two COF thin films (TpAzo and TpDPP) using F-F and S-F pathways on different supports such as borosilicate glass, FTO, silicon, Cu, metal, and ITO. Al
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- Author
- Ashok Kumar Mahato; Saikat Bag; Himadri Sekhar Sasmal; Kaushik Dey; Indrajit Giri; Mercedes Linares-Moreau; Carlos Carbonell; Paolo Falcaro; E. Bhoje Gowd; Ratheesh K Vijayaraghavan; Rahul Banerjee
- Publisher
- American Chemical Society (ACS)
- Published
- 2021
- Language
- EN
- Field
- Chemistry (Physical Sciences)