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Van der waals modulated spectral intensities: Application to infrared absorption by Bruno Linder is a Physics and Astronomy article available to read on EtoBox.
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## Abstract A formulation is presented of the effects of van der Waals interaction on infrared intensities. The theory takes account of induction and dispersion interactions (including charge interpenetration) and is applicable to fluids of arbitrary density. The transition moments are developed from generalized van der Waals‐induced moments, and expressions are obtained for the adsorption coefficient in terms of generalized charge densities and charge‐density (hyper)susceptibilities. Explicit expressions are given also of the integrated absorption coefficient in terms of multipoles, and (hyper)polarizabilities and their derivates, and the usefulness of this formulationin interpreting experimental data is illustrated by several examples. The relevance of the induction and dispersion interactions to allowed and to forbidden transitions made allowed is discussed.
Who reads Van der waals modulated spectral intensities: Application to infrared absorption?
It is typically read by researchers, students, and practitioners in Physics and Astronomy.
- Author
- Bruno Linder
- Publisher
- John Wiley and Sons; Wiley (John Wiley & Sons); John Wiley & Sons Inc.; Wiley (ISSN 0020-7608)
- Published
- 1991
- Field
- Physics and Astronomy (Physical Sciences)