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Design of Heterocomplementary H‐Bonding RAFT Agents – Towards the Generation of Supramolecular Star Polymers by Julien Bernard; Frédéric Lortie; Bernard Fenet is a Materials Science article available to read on EtoBox.

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## Abstract Supramolecular poly(vinyl acetate) PVAc 3‐arms stars were successfully generated by Reversible Addition–Fragmentation chain Transfer (RAFT)‐polymerized chains bearing hydrogen‐bonding heterocomplementary associating units. Chain Transfer Agents (CTA) bearing thymine‐ and diaminopyridine‐based units were first synthesized and proved to mediate efficiently the polymerization of VAc. The binding ability of the chains in solution was then demonstrated by ^1^H NMR and GPC measurements, proving the formation of the supramolecular stars. magnified image

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Author

Julien Bernard; Frédéric Lortie; Bernard Fenet

Publisher

John Wiley and Sons; Wiley (John Wiley & Sons); John Wiley & Sons Ltd.; Wiley (ISSN 1022-1336)

Published

2009

Language

EN

Field

Materials Science (Physical Sciences)