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The document presents elemental analysis and infrared spectral data for zirconium and hafnium complexes with various N(4)-alkyl, N(4)-dialkyl, and 3-azacyclothiosemicarbazone ligands. Table 1 shows the elemental composition in percent found and calculated for the complexes. Table 2 lists the infrared spectral bands observed for the ligands and their metal complexes, including bands corresponding to water, carbonyl, cyano, thiocarbonyl, metal-oxygen, and metal-nitrogen groups. The data provides characterizat

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