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One-pot Multi-substrate Enantioselective Conjugate Addition of Diethylzinc to Nitroalkenes by Ate Duursma; Adriaan J Minnaard; Ben L Feringa is a Chemistry article available to read on EtoBox.
What is One-pot Multi-substrate Enantioselective Conjugate Addition of Diethylzinc to Nitroalkenes about?
AbstractÐA multi-substrate approach is used in the copper-phosphoramidite catalyzed enantioselective conjugate addition of diethylzinc to nitroalkenes, using up to nine different nitroalkenes in a one pot procedure. The 18 products (9 times 2 enantiomers of nine different nitroalkanes) can be analyzed by chiral CG in a single run since on overlap in the peaks is observed. The obtained enantioselectivities are amongst the highest reported so far for the catalytic 1,4-addition of dialkylzinc reagents to nitroalkenes.
Who reads One-pot Multi-substrate Enantioselective Conjugate Addition of Diethylzinc to Nitroalkenes?
It is typically read by researchers, students, and practitioners in Chemistry.
- Author
- Ate Duursma; Adriaan J Minnaard; Ben L Feringa
- Publisher
- Elsevier Science; Elsevier ; Elsevier Ltd.; Elsevier BV (ISSN 0040-4020)
- Published
- 2002
- Language
- EN
- Field
- Chemistry (Physical Sciences)
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