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Atmospheric chemistry of C2F5CHO: mechanism of the C2F5C(O)O2 + HO2 reaction by M.P. Sulbaek Andersen; M.D. Hurley; T.J. Wallington; J.C. Ball; J.W. Martin; D.A. Ellis; S.A. Mabury is a Physics and Astronomy article available to read on EtoBox.
What is Atmospheric chemistry of C2F5CHO: mechanism of the C2F5C(O)O2 + HO2 reaction about?
Smog chamber/FTIR techniques were used to study the gas-phase reaction of C 2 F 5 C(O)O 2 with HO 2 radicals in 100-700 Torr of air, or O 2 , diluent at 296 K. The reaction proceeds by two pathways leading to formation of C 2 F 5 C(O)OH and O 3 in a yield of 24 AE 4% and C 2 F 5 C(O)O radicals, OH radicals and O 2 in a yield of 76 AE 4%. The gas phase reaction of C n F 2n þ 1 C(O)O 2 with HO 2 radicals offers a potential explanation for at least part of the observed environmental burden of fluorinated carboxylic acids, C n F 2n þ 1 C(O)OH. As part of this work an upper limit for the rate constant of reaction of Cl atoms with C 2 F 5 C(O)OH at 296 K was determined; k(Cl + C 2 F 5 C(O)OH) < 1 Â 10 À17 cm 3 molecule À1 s À1 .
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- Author
- M.P. Sulbaek Andersen; M.D. Hurley; T.J. Wallington; J.C. Ball; J.W. Martin; D.A. Ellis; S.A. Mabury
- Publisher
- Elsevier Science; Elsevier ; Elsevier BV (ISSN 0009-2614)
- Published
- 2003
- Language
- EN
- Field
- Physics and Astronomy (Physical Sciences)