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New Route to Alkylaluminum Hydroxides via Hydrolysis of Cyclopentadienylaluminum Complexes by Kinga Leszczyńska; Izabela D. Madura; Antoni R. Kunicki; Janusz Zachara; Magdalena Łoś is a Chemistry article available to read on EtoBox.
What is New Route to Alkylaluminum Hydroxides via Hydrolysis of Cyclopentadienylaluminum Complexes about?
A novel, very simple and effective synthetic method for the formation of alkylaluminum complexes with terminal hydroxy group via hydrolysis of cyclopentadienylaluminum compounds has been found. Investigations of the hydrolysis of cyclopentadienylaluminum complexes (L)Al(Me)Cp ( 1) and (L)Al(Et)Cp (2) (L = HC[(CMe)(2,6-i Pr 2 C 6 H 3 N)] 2 ) have shown that the reaction leads to the formation of (L)Al(Me)OH ( 3) and (L)Al(Et)OH (4), respectively. The high selectivity of the hydrolysis was revealed. The crystal structures of 1, 2 and 4 were determined.
Who reads New Route to Alkylaluminum Hydroxides via Hydrolysis of Cyclopentadienylaluminum Complexes?
It is typically read by researchers, students, and practitioners in Chemistry.
- Author
- Kinga Leszczyńska; Izabela D. Madura; Antoni R. Kunicki; Janusz Zachara; Magdalena Łoś
- Publisher
- Elsevier Science; Elsevier ; Elsevier BV (ISSN 0022-328X)
- Published
- 2007
- Language
- EN
- Field
- Chemistry (Physical Sciences)