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Solvolysis of TFMSC in Mixed Solvents by siyengar1447 is a document available to read on EtoBox.
1) The document investigates the solvolysis rates of trifluoromethanesulfonyl chloride (TFMSC) in water and aqueous mixtures of acetone, ethanol, and methanol at varying temperatures. 2) Grunwald-Winstein plots of the first-order rate constants show dispersion into three separate curves for the three aqueous mixtures, indicating different reaction mechanisms. 3) Using an extended Grunwald-Winstein equation that includes solvent nucleophilicity, the rate data correlates better and suggests the reaction p
- Author
- siyengar1447
- Language
- EN