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Can I read Temperature dependence of the reaction rate constants for O(3P) atoms with C2H4, C3H6 and NO(M = N2O), determined by a modulation technique on EtoBox?

Temperature dependence of the reaction rate constants for O(3P) atoms with C2H4, C3H6 and NO(M = N2O), determined by a modulation technique by R. Atkinson; J.N. Pitts Jr. is a Physics and Astronomy article available to read on EtoBox.

What is Temperature dependence of the reaction rate constants for O(3P) atoms with C2H4, C3H6 and NO(M = N2O), determined by a modulation technique about?

Ra?e constants for the reaction of 0(3P) atoms with CaH4, CaHB and NO(M = NpO) have been measured over the temperature range 300-392°K using a modulation-phase shifi technique. The Arrhenius expressions obtained are: C2H4, k2 = 3.37 X 10' exp[-(1270 -f 200)/RT] liter mole-' see-', CJH~, kz = 2.08 x 10' exp[\_(O f 300)/RT]liter mole-' set-', NOW = N\*O), k, = 9.6 X 10' exp[(900 \* 2OO)Pq liter' mole\* set-' . These temperature dependencies of k2 are in good agreement with recent flash photolysis-resonance fluorescence measurements, although Iower than previous literature values.

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Author
R. Atkinson; J.N. Pitts Jr.
Publisher
Elsevier Science; Elsevier ; Elsevier BV (ISSN 0009-2614)
Published
1974
Language
EN
Field
Physics and Astronomy (Physical Sciences)

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