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Catalytic Reductive Carboncarbon Bond-forming Reactions of Alkynes by Karen M. Miller; Carmela Molinaro; Timothy F. Jamison is a Chemistry article available to read on EtoBox.

What is Catalytic Reductive Carboncarbon Bond-forming Reactions of Alkynes about?

Enantioselective nickel/phosphine-catalyzed reductive coupling of alkynes and aldehydes provides rapid access to synthetically useful allylic alcohols with high enantiomeric excess. A related reaction involving epoxides is enantiospecific, transforming alkynes and chiral terminal epoxides into enantiomerically pure homoallylic alcohols containing a trisubstituted olefin of defined geometry. A gram-scale example of each of these processes is described.

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Author

Karen M. Miller; Carmela Molinaro; Timothy F. Jamison

Publisher

Elsevier Science; Elsevier ; Elsevier Ltd.; Elsevier BV (ISSN 0957-4166)

Published

2003

Language

EN

Field

Chemistry (Physical Sciences)