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INORGANIC CHEMISTRY-III,UNIT-II. Metal-ligand bonding in Transition Metal Complexes: Limitations of valance bondtheory, an elementary idea of crystal field theory, crystal field splitting in octahedral,tetrahedral and square planner complexes, factors affecting the crystal-field parameters.II. Thermodynamic and Kinetic Aspects of Metal Complexes: A brief outline ofthermodynamics stability of metal complexes and factors affecting the stability, stabilityconstants of complexes and their determination, substitution reactions of square planarcomplexes.UNIT-IIIII. Magnetic Properties of Transition Metal Complexes: Types of magnetic behavior,methods of determining magnetic susceptibility, spin-only formula, L-S coupling, correlationof s and effvalues, orbital contribution to magnetic moments, application of magneticmoment data for 3d-metal complexes.IV. Electronic spectra of Transition Metal Complexes: Types of electronic transitions,selection rules for d-d transitions, spectroscopic ground states, spectrochemical series, Orgel-energy level diagram for d1 and d9 states, discussion of the electronic spectrum of[Ti(H2O) 6] 3+ complex ion.UNIT-IIIV. Organometallic Chemistry: Definition, nom

Author

vikrant

Published

2021

Language

EN