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A Quantitative Study of Substituent Effects on Oxidative Cyclization of Some 2‐Aryl‐substituted Aldehyde Thiosemicarbazones Induced by Ferric Chloride and Cupric Perchlorate by Renato Noto; Paolo Lo Meo; Michelangelo Gruttadauria; Giuseppe Werber is a Chemistry article available to read on EtoBox.

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## Abstract As a development of our previous work, we performed a kinetic study of the oxidative cyclization reaction of some 2,4‐diaryl‐substituted aldehyde thiosemicarbazones 1a‐n induced by ferric chloride and by cupric perchlorate. The results of cyclization of 1a‐n were compared to those of the corresponding 2‐methyl derivatives. The kinetic data were analyzed by means of the Hammett's equation.

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Author

Renato Noto; Paolo Lo Meo; Michelangelo Gruttadauria; Giuseppe Werber

Publisher

Wiley

Published

1999

Language

EN

Field

Chemistry (Physical Sciences)