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Can I read Acid‐base properties of solid polyelectrolytes: Dissociation of cellulosic polyanions on EtoBox?
Acid‐base properties of solid polyelectrolytes: Dissociation of cellulosic polyanions by R. T. Shet; E. Y. Atanu is a Materials Science article available to read on EtoBox.
What is Acid‐base properties of solid polyelectrolytes: Dissociation of cellulosic polyanions about?
## Abstract The potentiometric titration behavior of nitrogen dioxide and periodate‐chlorite oxycellulose has been studied both in the presence and absence of sodium chloride. The apparent p__K__ values in general increase with increasing degree of dissociation, but the reverse is true for periodate‐chlorite oxycellulose in the absence of added salt. This behavior is interpreted in terms of electrostatic and hydrogen bonding interaction of carboxyl groups. The Gibbs–Donnan theory of polyaid dissociation was applied to calculate the intrinsic dissociation constant p__K__′~0~. Assuming a model having a uniform potential distributin throughout the fiber, good agreement with the expected value of 3.24 was found (compared to p__K__′~0~ = 3.25 calculated for periodate‐chlorite oxycellulose).
Who reads Acid‐base properties of solid polyelectrolytes: Dissociation of cellulosic polyanions?
It is typically read by researchers, students, and practitioners in Materials Science.
- Author
- R. T. Shet; E. Y. Atanu
- Publisher
- John Wiley and Sons; Wiley (John Wiley & Sons); Wiley (ISSN 0360-6376)
- Published
- 1982
- Language
- EN
- Field
- Materials Science (Physical Sciences)