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What is Enantioselective Aldol Reaction of Cyclohexanone about?
The document evaluates prolinamide and prolinethioamide organocatalysts for direct asymmetric aldol reactions between ketones and aromatic aldehydes under water and solvent-free conditions. Prolinethioamide 1d derived from L-proline and (R)-1-aminoindane is the most efficient, providing anti-aldol products in high yields and excellent diastereo- and enantioselectivities. Solvent-free conditions give slightly higher selectivity than using water.
- Author
- intata 24
- Language
- EN