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Phenylethanol Derivatives as Triplet Sensitizers for 1-Azidoadamantane by Ranaweera R. A. Upul Ranaweera; Sridhar Rajam; Anna D. Gudmundsdottir is a Chemistry article available to read on EtoBox.

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Laser flash photolysis, phosphorescence and density functional calculations were used to characterize the triplet excited states of phenylethanol derivatives 1, 2, 3 and 4. In acetonitrile, the triplet excited states of these alcohols were formed with rate constants on the order of ~10^7^ s^–1^ and decayed with rate constants between 10^5^ and 10^6^ s^–1^. The energies of these triplet excited states were between 80 and 83 kcal/mol. Furthermore, 3 can be used as a triplet sensitizer for alkyl azides to form triplet nitrene intermediates. Copyright © 2011 John Wiley & Sons, Ltd.

Who reads Phenylethanol Derivatives as Triplet Sensitizers for 1-Azidoadamantane?

Author

Ranaweera R. A. Upul Ranaweera; Sridhar Rajam; Anna D. Gudmundsdottir

Publisher

John Wiley and Sons; Wiley (John Wiley & Sons); John Wiley & Sons Inc.; Wiley (ISSN 0894-3230)

Published

2011

Language

EN

Field

Chemistry (Physical Sciences)