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The chemistry of O,N-diarylhydroxlamines - I by James R. Cox Jr.; Michael F. Dunn is a Chemistry article available to read on EtoBox.
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REARRANGEh!&lS from tne nitrogen atom of many N-substituted aniline6 intc the aromatic ring are known'. Among these, the rearrangemnt of hydrazobenzene to benzidine is intramolecular and requires diprotonation of the substrate', while the acid-catalyzed conversion of N-phenylhydroxylamine to cano e-aminophenol is intermolecular and requires monoprotonation of the stibstrate3. The theoretical interest of these reactions has prompted us to attempt the synthesis of O,N-diphenylhydroxylamine, (I). in order to investigate its behavior undei acidic conditions.
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- Author
- James R. Cox Jr.; Michael F. Dunn
- Publisher
- Elsevier Science; Elsevier ; Elsevier Ltd.; Elsevier BV (ISSN 0040-4039)
- Published
- 1963
- Language
- EN
- Field
- Chemistry (Physical Sciences)