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Spectroscopy studies of sandwich-type complex of silver(I) co-ordinated to nuclear fast red and adenine and its analytical applications by Yi Cui; Yi-Jun Gong; Li Su; Cheng-Ke Wu; Sheng-Bin Pang; Su-Ling Feng is a Chemistry article available to read on EtoBox.
What is Spectroscopy studies of sandwich-type complex of silver(I) co-ordinated to nuclear fast red and adenine and its analytical applications about?
A novel fluorometric method for the determination of adenine was proposed, based on the fluorescence quenching of a nuclear fast red-silver complex as a small molecule optical probe in the presence of adenine. The characteristic spectra of absorption, resonance Rayleigh scattering (RRS) and the fluorescence of the system were analysed. Adenine, Ag + and nuclear fast red formed a sandwichtype complex. The composition of the compound and the mechanisms of fluorescence quenching were discussed. The optimal conditions for the reaction and the effects of co-existing substances were also investigated. The quenched fluorescence intensity was proportional to the concentration of adenine in the range of 0.03-0.90 μg mL -1 , with the limit of detection of 0.023 μg mL -1 . The method was applied satisfactorily to the determination of adenine in synthetic samples, herring sperm DNA, human sera and vitamin B4 tablets with recoveries from 95.3 % to 105 %.
Who reads Spectroscopy studies of sandwich-type complex of silver(I) co-ordinated to nuclear fast red and adenine and its analytical applications?
It is typically read by researchers, students, and practitioners in Chemistry.
- Author
- Yi Cui; Yi-Jun Gong; Li Su; Cheng-Ke Wu; Sheng-Bin Pang; Su-Ling Feng
- Published
- 2015
- Language
- EN
- Field
- Chemistry (Physical Sciences)
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