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Structural Characterization of Some Coinage Metal(I) Thiosulfate Complexes, $\rm M^{1}\ {a}M\rm ^{2}\ {b}(X\ {c}) (S\ {2}O\ {3})\ {d}(\cdot eS)$ (M^1^ = Group 1 Cation, X = Univalent Anion, M^2^ = Cu^I^, Ag^I^, S = Solvent) by Eric J. Chan; Brian W. Skelton; Allan H. White is a Chemistry article available to read on EtoBox.

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## Abstract Building on previous single crystal X‐ray structure determinations for the group 1 salts of complex thiosulfate/univalent coinage metal anions previously defined for (NH~4~)~9~AgCl~2~(S~2~O~3~)~4~, NaAgS~2~O~3~·H~2~O and Na~4~[Cu(NH~3~)~4~][Cu(S~2~O~3~)~2~]·NH~3~, a wide variety of similar salts, of the form $\rm M^{1}\_{a}M\rm ^{2}\_{b}(X\_{c}) (S\_{2}O\_{3})\_{d}$, M^1^ = group 1 metal cation, M^2^ = univalent coinage metal cation (Cu, Ag), (X = univalent anion), most previously known, but some not, have been isolated and subjected to similar determinations. These have defined further members of the isotypic, tetragonal $I{\bar 4} {\rm 2}d \textrm{ }{\rm M^{1}\_{9}M^{2}X\_{2}(S\_{2}O\_{3})\_{4}({\equiv}M^{1}\_{9}X\_{2}[M^{2}}(S{\rm SO\_{3})\_{4}]{\equiv}2M^{1}X}.\textrm{ } {\rm M^{1}\_{7}[M^{2}}(S{\rm SO\_{3})\_{4}]}$ series, for M^1^ = NH~4~, M^2^ = Cu, Ag, X = NO~3~, Cl, Br, I, together with the K/Cu/NO~3~ complex, all containing the complex anion [M^2^(__S__SO~3~)~4~]^7−^ with M^2^ in an environment of $\rm {\bar 4}$ symmetry, Cu, Ag‐S typically __ca.__ 2.37, 2.58Å, with __quasi__‐tetrahedral S‐M‐S angular environments. Further salts of the form $\rm M^{1}\_{2n-1}M

Who reads Structural Characterization of Some Coinage Metal(I) Thiosulfate Complexes, $\rm M^{1}\ {a}M\rm ^{2}\ {b}(X\ {c}) (S\ {2}O\ {3})\ {d}(\cdot eS)$ (M^1^ = Group 1 Cation, X = Univalent Anion, M^2^ = Cu^I^, Ag^I^, S = Solvent)?

Author

Eric J. Chan; Brian W. Skelton; Allan H. White

Publisher

John Wiley and Sons; Wiley (John Wiley & Sons); Wiley - V C H Verlag GmbbH & Co.; Wiley (ISSN 0372-7874)

Published

2008

Language

EN

Field

Chemistry (Physical Sciences)