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Coordinating Ability of Methylpiperidine Dithiocarbamates Towards Platinum Group Metals by Gian Carlo Franchini; Aleardo Giusti; Carlo Preti; Lorenzo Tassi; Paolo Zannini is a Chemistry article available to read on EtoBox.

What is Coordinating Ability of Methylpiperidine Dithiocarbamates Towards Platinum Group Metals about?

rhodium(III), iridium(III), palladium(I1) and platinum(I1) dithiocarbamate complexes of the types M(Rdtc), and M(Rdtc), (Rdtc = 2-, 3-and 4-methylpiperidine dithiocarbamate) have been prepared and characterized by chemidal analyses, conductance measurements, electronic and IR spectral studies, magnetic measurements and thermal analyses (TG and DTG techniques). From the electronic absorption spectra the values of the ligand field parameters were determined; the nephelauxetic parameters are indicative of a strong covalency in the metal-ligand bond. All the complexes here reported are diamagnetic and nonconducting both in the solid state and in DMF solution.

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Author

Gian Carlo Franchini; Aleardo Giusti; Carlo Preti; Lorenzo Tassi; Paolo Zannini

Publisher

Elsevier Science; Elsevier ; Elsevier Ltd.; Elsevier BV (ISSN 0277-5387)

Published

1985

Language

EN

Field

Chemistry (Physical Sciences)