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Crystal structure and magnetic measurements of [Cr(en)3] [ZnCl4]Cl by J. Pons; J. Casabó; F. Palacio; M.C. Morón; X. Solans; Richard L. Carlin is a Chemistry article available to read on EtoBox.

What is Crystal structure and magnetic measurements of [Cr(en)3] [ZnCl4]Cl about?

The compound [Cr(en)a] [Z&lb] Cl has been synthesized by reaction of CrCls\*6HaO, Zn and [Cr(en)a]a(SO& in HCl. Its molecular and crystalline structure was determined by X-ray diffraction methods, being monoclinic, P2i/c, a = 21.215(3), b = 12.532(2), c = 13.707(2) A, fl= 95.21', V= 3629(2) hi3, D, = 1.738 g cme3, MW = 474.9, Z = 8, F(OO0) = 1928, h(Mo Kcr) = 0.7 1069 A, n(Mo Kol) = 27.04 cm-', 288 K. No significant exchange interactions between Cr(III) cations in the crystalline lattice were found. Curie-Weiss behavior was found in the three directions tested dg, = 2.06 + 0.02, ga = 2.08~0.

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Author

J. Pons; J. Casabó; F. Palacio; M.C. Morón; X. Solans; Richard L. Carlin

Publisher

Elsevier Science; Elsevier ; Elsevier BV (ISSN 0020-1693)

Published

1988

Language

EN

Field

Chemistry (Physical Sciences)