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Structural and Vibrational Properties of Betainium Perchlorate Monohydrate Crystal and Character of Its Hydrogen Bonds by Marek Ilczyszyn; Dorota Godzisz; Maria M. Ilczyszyn is a Chemistry article available to read on EtoBox.

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Betainium perchlorate monohydrate crystal ((CH 3 ) 3 NCH 2 COOH)(ClO 4 ) ́H 2 O) undergoes a continuous (second order) phase transition at ca. 180 K. X-ray data and vibrational spectroscopy studies at different temperatures are used for description of the phase transition mechanism, as well as of hydrogen bonds formed by water in this molecular system. Perturbation of monomer water by various surroundings (water vapour, low-temperature matrices, solvents, betaine-acid crystals) and properties of triple hydrogen bonds to water oxygen atom are discussed.

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Author

Marek Ilczyszyn; Dorota Godzisz; Maria M. Ilczyszyn

Publisher

Elsevier Science; Elsevier ; Elsevier BV (ISSN 0022-2860)

Published

2002

Language

EN

Field

Chemistry (Physical Sciences)