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A model to calculate the viscosity of silicate melts: Part III: Modification for melts containing alkali oxides by Wan-Yi Kim; Arthur D. Pelton; Sergei A. Decterov is a Engineering article available to read on EtoBox.

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## Abstract Our recently developed model to describe the viscosity of silicate melts is extended to describe and predict the viscosities of alkali-rich silicate melts. The model requires one additional binary parameter for each __M__ ~2~O–SiO~2~ system, where __M__ is an alkali metal, to a total of three binary parameters per binary system alkali oxide – silica. In addition to unary and binary parameters, the model requires two ternary parameters for each alumina-containing ternary system __M__O__x__–Al~2~O~3~ –SiO~2~, where __M__O__x__ is a basic oxide, to describe the viscosity maxima in these ternary systems due to the Charge Compensation Effect. The viscosity of multicomponent melts and of ternary melts __M__O__x__–__N__O__y__–SiO~2~, where __M__O__x__ and __N__O__y__ are basic oxides, is predicted by the model solely from the unary, binary and ternary parameters. The available viscosity data for the alkali-containing subsystems of the Al~2~O~3~–CaO–MgO–Na~2~O–K~2~O–SiO~2~ system are reviewed. The model reproduces the experimental data for binary and ternary melts and predicts the viscosities of multicomponent melts within experimental error limits. In particular, the viscositi

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Author
Wan-Yi Kim; Arthur D. Pelton; Sergei A. Decterov
Publisher
Walter de Gruyter GmbH
Published
2012
Language
EN
Field
Engineering (Physical Sciences)

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