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A high-temperature mass spectrometric study of the vaporization processes of fluxes based on CaO–CaCl2 and CaO–CaF2 systems by V. L. Stolyarova; S. Seetharaman; D. Svard; G. A. Semenov is a Chemistry article available to read on EtoBox.

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The high-temperature Knudsen effusion method was used to study the vaporization processes and thermodynamic properties of fluxes based on CaO-CaCl 2 and CaO-CaF 2 systems with additions of Al, Al 2 O 3 in the temperature range 800-2240 K. The composition of vapour and the partial pressures of vapour species as a function of temperature and vaporization time of fluxes were obtained. Vaporization enthalpies of components and dependences of partial pressures as a function of temperature are suggested for practical needs based on the experimental results. Reliability of the data obtained in the present study was confirmed by comparison with the reference values for Au, CsCl, CaCl 2 and CaF 2 .

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Author

V. L. Stolyarova; S. Seetharaman; D. Svard; G. A. Semenov

Publisher

John Wiley and Sons; Wiley (John Wiley & Sons); John Wiley & Sons Inc.; Wiley (ISSN 0951-4198)

Published

1998

Language

EN

Field

Chemistry (Physical Sciences)