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There has been considerable recent interest in alkylphosphinate esters as substrates for study of displacement at phosphorus. ~-4 Interpretation of some of this data is complicated by the problem of possible attack at alkyl carbon rather than phosphorus. We report here data on relative rates of hydrolysis in acyclic and cyclic compounds and elucidation of the position of attack by H1aO-in both series through use of no-enriched water.

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Author

Paul Haake; Robert D. Cook; Wolfgang Schwarz; D.R. McCoy

Publisher

Elsevier Science; Elsevier ; Elsevier Ltd.; Elsevier BV (ISSN 0040-4039)

Published

1968

Language

EN

Field

Chemistry (Physical Sciences)