Can I read Structural studies of diorganotin(IV) sulphonates The crystal structures of [(n-C4H9)2Sn{μ-OSO2C6H2(CH3)3}2]n and its partially hydrolyzed product [(n-C4H9)2Sn{(μ-OH)(μ-OSO2C6H2(CH3)3)}]n on EtoBox?

Structural studies of diorganotin(IV) sulphonates The crystal structures of [(n-C4H9)2Sn{μ-OSO2C6H2(CH3)3}2]n and its partially hydrolyzed product [(n-C4H9)2Sn{(μ-OH)(μ-OSO2C6H2(CH3)3)}]n by Ramesh Kapoor; Anand Gupta; Pratibha Kapoor; Paloth Venugopalan is a Chemistry article available to read on EtoBox.

What is Structural studies of diorganotin(IV) sulphonates The crystal structures of [(n-C4H9)2Sn{μ-OSO2C6H2(CH3)3}2]n and its partially hydrolyzed product [(n-C4H9)2Sn{(μ-OH)(μ-OSO2C6H2(CH3)3)}]n about?

The X-ray crystal structures of [(n-C 4 H 9 ) 2 Sn{m-OSO 2 C 6 H 2 (CH 3 ) 3 } 2 ] n (1) and [(n-C 4 H 9 ) 2 Sn{(m-OH)(m-OSO 2 C 6 H 2 (CH 3 ) 3 )}] n (2) were determined to delineate the coordination behaviour of the sulphonate group with tin(IV) and to evaluate the metal sulphonate bonding interactions. The synthesis of 1 has been achieved by azeotropic dehydration of di-n-butyltin(IV) oxide and mesitylenesulphonic acid. 1 is polymeric containing six-coordinate tin and crystallizes from anhydrous toluene in the orthorhombic space group P2 1 2 1 2 with unit cell dimensions a= 12.555(1), b= 21.238(1), c= 5.415(1) A , ; Z =2; R, 0.0236 and wR, 0.0607 for 1281 observed reflections. The structure exhibits highly symmetrical bridging bidentate mesitylenesulphonate groups and is made up of an infinite array of (n-C 4 H 9 ) 2 SnO 4 moieties. Compound 1 hydrolyzes very slowly to [(n-C 4 H 9 ) 2 Sn{(m-OH)(m-OSO 2 C 6 H 2 (CH 3 ) 3 )}] n (2), when kept in CH 3 OH-CHCl 3 mixture at room temperature for 35 days. Crystals of 2 are monoclinic with space group P2 1 /m and unit cell dimensions a=10.040(1), b= 14.500(1), c= 13.978(1) A , ; i= 91.58(1)°; Z =4; R, 0.0226; wR, 0.0592 for 2725 observe

Who reads Structural studies of diorganotin(IV) sulphonates The crystal structures of [(n-C4H9)2Sn{μ-OSO2C6H2(CH3)3}2]n and its partially hydrolyzed product [(n-C4H9)2Sn{(μ-OH)(μ-OSO2C6H2(CH3)3)}]n?

Author

Ramesh Kapoor; Anand Gupta; Pratibha Kapoor; Paloth Venugopalan

Publisher

Elsevier Science; Elsevier ; Elsevier BV (ISSN 0022-328X)

Published

2001

Language

EN

Field

Chemistry (Physical Sciences)