Can I read Complexes of organometallic compounds: XLII. Spectroscopic studies of N,N′-ethylenebis(acetylacetoneimine) and N,N′-ethylenebis(salicylideneimine) adducts of organolead(IV) and organothallium(III) on EtoBox?

Complexes of organometallic compounds: XLII. Spectroscopic studies of N,N′-ethylenebis(acetylacetoneimine) and N,N′-ethylenebis(salicylideneimine) adducts of organolead(IV) and organothallium(III) by L Pellerito; Rosalba Cefalù; Marta Airoldi is a Chemistry article available to read on EtoBox.

What is Complexes of organometallic compounds: XLII. Spectroscopic studies of N,N′-ethylenebis(acetylacetoneimine) and N,N′-ethylenebis(salicylideneimine) adducts of organolead(IV) and organothallium(III) about?

The nature of the l/l adducts formed from the ligands N,N '-ethylenebis-(acetylacetoneirnine) and N,N'-ethylenebis(salicylideneimine) witI> Ph2PbCll and PhTlC12 was investigated in the solid state and in methanol solution by IR, electronic and PMR spectroscopy, and by osmometry and conductivity. The adducts exist only in the soli. state and dissociate fully into the parent compounds in solution. Polymeric structures are proposed for the solids, in which bis-monodentate ligands bridge the organometallic moieties.

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Author

L Pellerito; Rosalba Cefalù; Marta Airoldi

Publisher

Elsevier Science; Elsevier ; Elsevier BV (ISSN 0022-328X)

Published

1974

Language

EN

Field

Chemistry (Physical Sciences)