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Supramolecular architectures sustained by arene-C–H...π(quasi-chelate ring) interactions in the crystal structures of copper(I) complexes by Julio Zukerman-Schpector; Chien Ing Yeo; Edward R.T. Tiekink is a Chemistry article available to read on EtoBox.

What is Supramolecular architectures sustained by arene-C–H...π(quasi-chelate ring) interactions in the crystal structures of copper(I) complexes about?

## Abstract A review of the crystallographic literature is presented whereby structures featuring a quasi-six-membered chelate ring of the type {CuCl...HNCS} were evaluated for the presence of intermolecular C–H...π(quasi-chelate) interactions. These are shown to stabilise crystal structures leading to zero-, one-, two- and even three-dimensional architectures. Details of these interactions are described and a comparison to analogous interactions formed intramolecularly has been made. The C–H...π(quasi-chelate) interactions in these structures occur in one-third of structures where such contacts can potentially form.

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Author

Julio Zukerman-Schpector; Chien Ing Yeo; Edward R.T. Tiekink

Publisher

Walter de Gruyter GmbH

Published

2015

Language

EN

Field

Chemistry (Physical Sciences)