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What is Isocyanide-Based Multicomponent Reaction about?
This document presents a metal-free cascade reaction involving α-acyloxylation/carboxamidation of I(III)/S(VI)-ylides, carboxylic acids, and isonitriles, resulting in the synthesis of unsymmetrical α,α-disubstituted ketones and functionalized pyrroles with high yields. The study also reports an unexpected [3 + 1+1] cyclization involving I(III)/S(VI)-ylides and ethyl isocyanoacetate, showcasing the method
- Author
- backshieldattacker
- Language
- EN