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Syntheses and characterization of copper(II) complexes of bis(acetylacetone)trimethylenediimine by Yue-Peng Cai; Cheng-Yong Su*; An-wu Xu; Bei-Sheng Kang; Ye-Xiang Tong; Han-Qin Liu; Sun Jie is a Chemistry article available to read on EtoBox.
What is Syntheses and characterization of copper(II) complexes of bis(acetylacetone)trimethylenediimine about?
Copper(II) complexes [Cu(acactn)H 2 O] 2 (1) and [Cu 2 (acactn) 2 KClO 4 ] 2 (2), where H 2 acactn is a tetradentate Schiff base bis(acetylacetone)trimethylenediimine, have been prepared and characterized by IR, CV and X-ray single crystal structure analyses. The ligand H 2 acactn is strongly metallophilic to stabilize Cu(II) ion with a square planar N 2 O 2 coordination environment. Complex 1 can be seen as a hydrogen-bonded dimer of building block Cu(acactn) via bridging water molecules, while complex 2 is a tetrametric adduct of [Cu(acactn)] moiety and KClO 4 , in which K + and ClO 4 -are the bridging-groups. Electrochemical studies displayed that Cu(II)/Cu(I) is an irreversible one-electron reduction process.
Who reads Syntheses and characterization of copper(II) complexes of bis(acetylacetone)trimethylenediimine?
It is typically read by researchers, students, and practitioners in Chemistry.
- Author
- Yue-Peng Cai; Cheng-Yong Su*; An-wu Xu; Bei-Sheng Kang; Ye-Xiang Tong; Han-Qin Liu; Sun Jie
- Publisher
- Elsevier Science; Elsevier ; Elsevier Ltd.; Elsevier BV (ISSN 0277-5387)
- Published
- 2001
- Language
- EN
- Field
- Chemistry (Physical Sciences)