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Can I read The [1,2]-thio-Wittig rearrangement: evidence for a radical mechanism and its suppression on EtoBox?
The [1,2]-thio-Wittig rearrangement: evidence for a radical mechanism and its suppression by Paola Bertolli; Robert D. Farley; Matthew D. Fletcher; Peter N. Horton; Michael B. Hursthouse; Cristina Paradela; Bernhard von Vacano is a Chemistry article available to read on EtoBox.
What is The [1,2]-thio-Wittig rearrangement: evidence for a radical mechanism and its suppression about?
The lithium enolate formed from methyl S-trityl mercaptoacetate can be C-alkylated in high yield at or below À40 °C, but at higher temperatures the [1,2]-thio-Wittig rearrangement of the enolate is the predominant process; ESR evidence indicates that this rearrangement occurs by a radical mechanism.
Who reads The [1,2]-thio-Wittig rearrangement: evidence for a radical mechanism and its suppression?
It is typically read by researchers, students, and practitioners in Chemistry.
- Author
- Paola Bertolli; Robert D. Farley; Matthew D. Fletcher; Peter N. Horton; Michael B. Hursthouse; Cristina Paradela; Bernhard von Vacano
- Publisher
- Elsevier Science; Elsevier ; Elsevier Ltd.; Elsevier BV (ISSN 0040-4039)
- Published
- 2006
- Language
- EN
- Field
- Chemistry (Physical Sciences)