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Can I read Phase polymorphism of [Co(DMSO)6](ClO4)2 studied by differential scanning calorimetry on EtoBox?
Phase polymorphism of [Co(DMSO)6](ClO4)2 studied by differential scanning calorimetry by A Migdał-Mikuli; E. Szostak is a Materials Science article available to read on EtoBox.
What is Phase polymorphism of [Co(DMSO)6](ClO4)2 studied by differential scanning calorimetry about?
Five solid phases of [Co(DMSO) 6 ](ClO 4 ) 2 have been detected by differential scanning calorimetry (DSC). Specifically, the phase transitions were detected between the following solid phases: metastable KIII ↔ overcooled K0 at T C4 = 329 K, stable KIb → stable KIa at T C3 = 350 K, metastable KII ↔ overcooled K0 at T C2 = 363 K and stable KIa → stable K0 at T C1 = 377 K. The title compound melts gradually in three steps with final melting point at T m = 495 K. From the entropy changes of the melting point and phase transitions it can be concluded that phases K0 and overcooled K0 are orientationally dynamically disordered phases. Stable phases KIa, KIb and metastable phase KIII are ordered solid phases. Metastable phase KII is probably a solid phase with a high degree of orientational dynamical disorder.
Who reads Phase polymorphism of [Co(DMSO)6](ClO4)2 studied by differential scanning calorimetry?
It is typically read by researchers, students, and practitioners in Materials Science.
- Author
- A Migdał-Mikuli; E. Szostak
- Publisher
- Elsevier Science; Elsevier ; Elsevier BV (ISSN 0040-6031)
- Published
- 2005
- Language
- EN
- Field
- Materials Science (Physical Sciences)