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Preface 5 Contents 6 1 Diffusion of Water in Adhesives 7 Abstract 7 1...Introduction 8 2...Fick’s 1st Law of Diffusion 8 3...Fick’s 2nd Law of Diffusion 9 4...Concentration-Distance Profile Across a Long Layer of Adhesive 9 5...Concentrations Within a Rectangular Lap Joint 10 6...Permeation Diffusion and Solubility 10 7...Characteristics of Fickian Sorption 12 8...Measurement of P, D and S 13 9...Water and Water Vapour 13 9.1 Water and Saturated Vapour 13 9.2 Variable Humidity 14 10...Sorption Data 14 10.1 Fickian Sorption 14 10.2 Non-Fickian Sorption 15 10.3 Salt Solutions 16 10.4 Isotherms 17 10.5 Films and Joints 18 11...Effect of Temperature 19 12...How Water Changes the Properties of Adhesives 20 12.1 Glass Transition Temperature 20 12.2 Cracks, Crazes and Voids 21 12.3 Mechanical Properties 22 13...Non-Structural Adhesives 22 13.1 Silicones 22 13.2 Isocyanates 23 14...Concluding Remarks 23 References 24 2 Water and Ions at Polymer/Metal Interfaces 26 Abstract 26 1...Introduction 27 2...Water at Polymer/Oxide Interfaces 27 2.1 Water Adsorption on Oxide Surfaces 27 2.2 Molecule and Polymer Adsorption on Water Covered Metal Oxides for the Investigation of Adhesion Forces 28 2.3

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