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1) Ni2(BDC)2(DABCO) metal-organic framework was synthesized using Ni(II) ions, 1,4-benzenedicarboxylic acid, and 1,4-diazabicyclo[2.2.2]octane under solvothermal conditions. 2) This MOF was tested as a heterogeneous catalyst for the cycloaddition of CO2 and epoxides to produce cyclic carbonates without solvent under mild conditions. 3) Characterization of the MOF showed it had a three dimensional open framework structure and was stable up to the reaction temperature of 100°C.

Author

Catalin

Language

EN