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What is Thermodynamic Perturbation Theory for Liquids about?

The document discusses the thermodynamic perturbation theory of simple liquids, highlighting that the series expansion for the Helmholtz free energy begins with a second-order term rather than the first, which is a significant deviation from traditional understanding. It emphasizes that the applicability of this theory is more influenced by many-particle correlations in the unperturbed system rather than the smallness of the perturbation potential. The paper also addresses challenges in applying this theory

Author

ai09.11.00

Language

EN