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Structure of Ga~2~O~3~(ZnO)~6~: a member of the homologous series Ga~2~O~3~(ZnO)~ m ~ by Yuichi Michiue; Noboru Kimizuka; Yasushi Kanke is a Chemistry article available to read on EtoBox.

What is Structure of Ga~2~O~3~(ZnO)~6~: a member of the homologous series Ga~2~O~3~(ZnO)~ m ~ about?

The structure of Ga~2~O~3~(ZnO)~6~ was determined using single-crystal X-ray diffraction techniques in the space group __Cmcm__. The metal ion sublattice resembles some of the Zn ions in the wurtzite ZnO structure. The oxygen ion sublattice in Ga~2~O~3~(ZnO)~6~ also resembles some of the O ions in ZnO. Structural relationships between Ga~2~O~3~(ZnO)~6~ and ZnO are discussed, illustrating the process for obtaining the centrosymmetric Ga~2~O~3~(ZnO)~6~ structure from the noncentrosymmetric ZnO. Structures of phases in the homologous series Ga~2~O~3~(ZnO)~__m__~ are predicted on the basis of the structural data for Ga~2~O~3~(ZnO)~6~. The structures of even __m__ are constructed by simply extending the structure units seen in Ga~2~O~3~(ZnO)~6~, while those of odd __m__ consist of structure units which are of different types from those used for even __m__.

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Author

Yuichi Michiue; Noboru Kimizuka; Yasushi Kanke

Publisher

International Union of Crystallography; Blackwell Publishing Inc.; International Union of Crystallography (IUCr) (ISSN 0108-7681)

Published

2008

Language

EN

Field

Chemistry (Physical Sciences)