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Can I read Configurational rearrangements in cis-M(AA)2X2, cis-M(AA)2XY, and cis-M(AB)2X2 complexes. 10. The cis-M(AB)2X2 system - diastereotopic probe on the X ligands on EtoBox?
Configurational rearrangements in cis-M(AA)2X2, cis-M(AA)2XY, and cis-M(AB)2X2 complexes. 10. The cis-M(AB)2X2 system - diastereotopic probe on the X ligands by Nick Serpone; Douglas G. Bickley is a Chemistry article available to read on EtoBox.
What is Configurational rearrangements in cis-M(AA)2X2, cis-M(AA)2XY, and cis-M(AB)2X2 complexes. 10. The cis-M(AB)2X2 system - diastereotopic probe on the X ligands about?
Diastereotopic probes have been incorporated on the X ligands of M(AB),XZ, where AB is an unsymmetrical bidentate lipand. The cpmplexes Ti(bzach -(O'C3H7)Z and Ti(bzac)z (2,6-'Pr2 C6 H3 O)? have been prepared (bzac = anion of benzoylacetone) and their stereochemistry characterized by nuclear magnetic resonance spectroscopy. The complexes adopt the cis-XZ geometry. These G-type complexes undergo terminal group exchange (and probably) in parallel with inversion of configuration. The latter, however, was not confined because of unresolved diastereotopic splittings. The averaging set for the rearrangement phenomena is identified as A: and the rearrangements are discussed in terms of twist motions about the C, axes of the octahedral framework and bond rupture.
Who reads Configurational rearrangements in cis-M(AA)2X2, cis-M(AA)2XY, and cis-M(AB)2X2 complexes. 10. The cis-M(AB)2X2 system - diastereotopic probe on the X ligands?
It is typically read by researchers, students, and practitioners in Chemistry.
- Author
- Nick Serpone; Douglas G. Bickley
- Publisher
- Elsevier Science; Elsevier ; Elsevier BV (ISSN 0020-1693)
- Published
- 1982
- Language
- EN
- Field
- Chemistry (Physical Sciences)