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Effect of silver doping on the TiO2 for photocatalytic reduction of CO2 by K. Kočí; K. Matějů; L. Obalová; S. Krejčíková; Z. Lacný; D. Plachá; L. Čapek; A. Hospodková; O. Šolcová is a Energy article available to read on EtoBox.

What is Effect of silver doping on the TiO2 for photocatalytic reduction of CO2 about?

a b s t r a c t Pure TiO 2 and various silver-enriched TiO 2 powders were prepared by the sol-gel process controlled in the reverse micellar environment. The catalysts were tested in CO 2 photocatalytic reduction and characterized by X-ray diffraction (XRD), nitrogen adsorption measurement and UV-vis. Methane and methanol were the main reduction products. The yield of methane and methanol increases when modifying the TiO 2 by silver incorporation is caused by two mechanisms: up to 5% of Ag in TiO 2 the Ag impurity band inside the TiO 2 bandgap decreases the absorption edge and increases so the electron-hole pair generation, above 5% of Ag in TiO 2 Ag metallic clusters are formed in TiO 2 crystals with Shottky barrier at the metal-semiconductor interface, which spatially separates electron and holes and increases their lifetime (decreases probability of their recombination).

Who reads Effect of silver doping on the TiO2 for photocatalytic reduction of CO2?

It is typically read by researchers, students, and practitioners in Energy.

Author
K. Kočí; K. Matějů; L. Obalová; S. Krejčíková; Z. Lacný; D. Plachá; L. Čapek; A. Hospodková; O. Šolcová
Publisher
Elsevier Science; Elsevier ; Elsevier BV (ISSN 0926-3373)
Published
2010
Language
EN
Field
Energy (Physical Sciences)

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