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This document reports the synthesis and characterization of a diphosphorus complex of uranium(IV), marking the first instance of such a complex involving heavier group 15 homologs. The study reveals that the diphosphorus ligand is activated to its dianionic form and demonstrates unique U-P p-bonding interactions. Preliminary reactivity studies indicate the potential for conversion of this complex into uranium cyclo-P3 derivatives, highlighting the significance of diphosphorus chemistry in f-element research
- Author
- shu748242
- Language
- EN