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Synthesis, Structure and Characterization of Dinuclear Pentacoordinate Molybdenum(V) Complexes with Thiosemicarbazone Ligands by Višnja Vrdoljak; Dalibor Milić; Marina Cindrić; Dubravka Matković-Čalogović; Jana Pisk; Marina Marković; Predrag Novak is a Chemistry article available to read on EtoBox.

What is Synthesis, Structure and Characterization of Dinuclear Pentacoordinate Molybdenum(V) Complexes with Thiosemicarbazone Ligands about?

## Abstract New dinuclear pentacoordinate molybdenum(V) complexes, [Mo~2~^V^O~3~L~2~] [L = thiosemicarbazonato ligand: C~6~H~4~(O)CH:NN:C(S)NH__R__′ and C~10~H~6~(O)CH:NN:C(S)NH__R__′; __R__′ = H, CH~3~, C~6~H~5~) were obtained either by oxygen atom abstraction from Mo^VI^O~2~L with triphenylphosphine or by using [Mo~2~O~3~(acac)~4~] in the reaction with the corresponding ligands H~2~L. Crystal and molecular structure of [Mo~2~O~3~{C~6~H~4~(O)CH:NN:C(S)NHC~6~H~5~}~2~]·CH~3~CN has been determined by the single‐crystal X‐ray diffraction method.

Who reads Synthesis, Structure and Characterization of Dinuclear Pentacoordinate Molybdenum(V) Complexes with Thiosemicarbazone Ligands?

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Author
Višnja Vrdoljak; Dalibor Milić; Marina Cindrić; Dubravka Matković-Čalogović; Jana Pisk; Marina Marković; Predrag Novak
Publisher
John Wiley and Sons; Wiley (John Wiley & Sons); Wiley - V C H Verlag GmbbH & Co.; Wiley (ISSN 0372-7874)
Published
2009
Language
EN
Field
Chemistry (Physical Sciences)