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Effect of Chain Length of Self-assembled Monolayers in Dip-pen Nanolithography Using Molecular Dynamics Simulations by Cheng-Da Wu; Te-Hua Fang; Jen-Fin Lin is a Chemistry article available to read on EtoBox.

What is Effect of Chain Length of Self-assembled Monolayers in Dip-pen Nanolithography Using Molecular Dynamics Simulations about?

The pattern transfer mechanism of an alkanethiol self-assembled monolayer (SAM) with different chain lengths during the dip-pen nanolithography (DPN) process and pattern characterizations are studied using molecular dynamics (MD) simulations. The mechanisms of molecular transference, alkanethiol meniscus characteristics, surface adsorbed energy, transfer number, and pattern formation are evaluated during the DPN process at room temperature. The simulation results clearly show that the molecular transfer ability in DPN is strongly dependent on the chain length. Shorter molecules have significantly better transport and diffusion abilities between the meniscus and substrate surface, and the transport period can be maintained longer. The magnitude of adsorbed energy increases with chain length, so many more molecules can be transferred to the surface when shorter molecules are used. After deposition, the magnitude of the adsorbed area and pattern height decrease with increasing chain length.

Who reads Effect of Chain Length of Self-assembled Monolayers in Dip-pen Nanolithography Using Molecular Dynamics Simulations?

It is typically read by researchers, students, and practitioners in Chemistry.

Author
Cheng-Da Wu; Te-Hua Fang; Jen-Fin Lin
Publisher
Elsevier Science; Elsevier ; Elsevier Inc.; Elsevier BV (ISSN 0021-9797)
Published
2011
Language
EN
Field
Chemistry (Physical Sciences)

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